On the spontaneous induction of chirality in the preparation of Werner's complex cis-CoBrNH3en2Br2Electronic supplementary information (ESI) available: Table of structural data. See DOI: 10.1039/b601530a

Autor: Guo, Fang, Casadesus, Meritxell, Cheung, Eugene Y., Coogan, Michael P., Harris, Kenneth D. M.
Zdroj: Chemical Communications; 2006, Vol. 2006 Issue: 17 p1854-1856, 3p
Abstrakt: The product obtained directly from the standard reaction to produce Werner's complex cis-CoBrNH3en2Br2is shown, viastructure determination from powder X-ray diffraction data, to be a racemic crystalline phase; implications of this observation in relation to previous reports that this reaction leads to significant enantiomeric excesses are discussed.
Databáze: Supplemental Index