| Autor: |
Minkin, Vladimir I., Mikhailov, Igor E., Dushenko, Galina A., Zschunke, Adolf |
| Zdroj: |
Russian Chemical Reviews; December 2003, Vol. 72 Issue: 10 p867-897, 31p |
| Abstrakt: |
Data on circumambulatory rearrangements caused by rapid migrations of substituents formed by Group 1317 elements around three- to nine-membered cyclopolyenes are generalised and systematised. Depending on the ring size, the nature of the migrating group, substituents in the ring and the medium, the rate constants of circumambulatory rearrangements vary over a wide range from 106 to 108 s1 at room temperature. Particular attention is given to analysis of the mechanisms of these rearrangements ([1, j]-, [2,3]- and [3,3]-sigmatropic shifts, haptotropic rearrangements and ionisationrecombination) and to the correlation of these mechanisms with the structural characteristics of the compounds that undergo rearrangements. The bibliography includes 241 references. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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