Kinetic and stereospecific manifestations of a set of active centres in butadiene polymerization under the action of a catalytic system based on NdCl3·3TBP

Autor: Monakov, Yurii B., Sabirov, Zufar M., Duvakina, Nina V., Urazbaev, Vadim N., Ponomareva, Olga A.
Zdroj: Mendeleev Communications; August 1, 2001, Vol. 11 Issue: 4 p157-159, 3p
Abstrakt: The unusual dependence of butadiene conversion and polymer microstructure on the ratio Mg/Nd or Al/Nd during the polymeriza-tion of butadiene under the action of NdCl3·3TBP–AlBu3i–MgBu(i-C8H17) can be explained by the formation of a set of active centres in the catalytic system.
Databáze: Supplemental Index
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