An unusual Bamford-Stevens reaction of 17-toluenesulfonylhydrazono- 3β-acetoxy-14α-hydroxyandrost-5-ene

Autor: Khripach, Vladimir V., Zhabinskii, Vladimir N., Kotyatkina, Anna I., Fando, Galina P., Lyakhov, Alexander S., Govorova, Alla A., Louw, Jaap van der, Groen, Marinus B., Groot, Aede de
Zdroj: Mendeleev Communications; August 1, 2001, Vol. 11 Issue: 4 p144-145, 2p
Abstrakt: The Bamford-Stevens reaction of 17-toluenesulfonylhydrazono-3β-acetoxy-14α-hydroxyandrost-5-ene was found to proceed with migration of the 18-methyl group and formation of a 13,14-epoxide.
Databáze: Supplemental Index