| Autor: |
Broomhead, JA, Greenwood, R, Pienkowski, W, Sterns, M |
| Zdroj: |
Australian Journal of Chemistry; 1986, Vol. 39 Issue: 11 p1895-1900, 6p |
| Abstrakt: |
The title complex is prepared either photochemically from pyridine-2-thiol and W(CO)6 or thermally from WBr2(CO)4. The molecular structure of this air-stable, diamagnetic compound shows an octahedral environment for the metal. The ligand is sulfur-bound only and the pyridine nitrogen is protonated. Crystals are monoclinic, space group P21/c with a 722.8(1), b 1375.5(4), c 1306.7(2) pm, β 98.815(5)° V 1.2839(5)×109 pm3 and Z 4; 2294 data were refined to R 0.026, Rw 0.032. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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