Autor: |
Clezy, PS, Hai, TT, Henderson, RW, Thuc, LV |
Zdroj: |
Australian Journal of Chemistry; 1980, Vol. 33 Issue: 3 p585-597, 13p |
Abstrakt: |
A mixture of acetic and sulfuric acids converts haematoporphyrin into a complex mixture of porphyrins of which the main product has been characterized as the diacetate (1g). Other compounds identified in the reaction mixture were the known vinylporphyrins (1b-d), (1h) and (li) and the isomeric monoacetoxyethyl(monohydroxyethyl)porphyrins (11) and (1m). Analysis of the reaction mixture was complicated by the presence of 1'-ethoxyethyl derivatives (1e) or (1f), (1j) and (1k)which presumably arose by solvolysis of the corresponding acetate with ethanol present in the chloroform used for the chromatographic separation. |
Databáze: |
Supplemental Index |
Externí odkaz: |
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