Stereoselective Reduction of 3-O-Hexofuranosyl S-Methyl Dithiocarbonates with Tributyltin Deuteride
| Autor: | Patroni, JJ, Stick, RV |
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| Zdroj: | Australian Journal of Chemistry; 1979, Vol. 32 Issue: 2 p411-416, 6p |
| Abstrakt: | The reduction of several 3-O-hexofuranosyl (gluco, allo, galacto, gulo) S-methyl dithiocarbonates with tributyltin deuteride leads to highly stereoselective syntheses of 3-deoxy-[3-2H]hexofuranoses.Correspondingly, the reduction of the 3-O-[3-2H]hexofuranosyl (allo, gulo) S-methyl dithiocarbonates with tributyltin hydride leads to the epimeric (C3) 3-deoxy-[3-2H]hexofuranoses, and the reduction with tributyltin deuteride leads to the 3-deoxy-[3,3-2H2]hexofuranose |
| Databáze: | Supplemental Index |
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