Photo-induced elimination in some aporphinium salts.
| Autor: | Bremner, JB, Winzenberg, KN |
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| Zdroj: | Australian Journal of Chemistry; 1978, Vol. 31 Issue: 2 p313-320, 8p |
| Abstrakt: | Ultraviolet irradiation of (+)-glaucine methiodide in methanol gave the elimination product 1-[2?-(N,N-dimethylaminoethyl)]-3,4,6,7- tetramethoxyphenanthrene in good yield. Analogous products were obtained from the ethiodide and benzylbromide salts of this aporphine alkaloid, and from quaternary salts of (+)-boldine and (-)-O,O?- dimethylapomorphine. This photoelimination reaction was also applied to the hydrochloride salts of (+)-glaucine and (+)-boldine. |
| Databáze: | Supplemental Index |
| Externí odkaz: |
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