The electronic spectra of binuclear molybdenum(II) carboxylates.
| Autor: | Dubicki, L, Martin, RL |
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| Zdroj: | Australian Journal of Chemistry; 1969, Vol. 22 Issue: 8 p1571-1581, 11p |
| Abstrakt: | The electronic spectra of binuclear molybdenum(II) acetate, benzoate, p-fluorobenzoate, and pentafluorobutyrate show intense absorption at ≈ 30000cm-1 which may, in part, be due to strong Mo-Mo bonding. The binuclear structure is characterized by a weak band at ≈ 23000 cm-1 which displays extensive vibrational fine structure. A semi-empirical molecular orbital calculation is used as an aid in the interpretation of the spectra. |
| Databáze: | Supplemental Index |
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