The ligand field spectra of trinuclear chromium(III) and iron(III) basic acetates.
| Autor: | Dubicki, L, Martin, RL |
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| Zdroj: | Australian Journal of Chemistry; 1969, Vol. 22 Issue: 4 p701-707, 7p |
| Abstrakt: | The visible spectra of trinuclear chromium(III) acetates [Cr3O(CH3CO2)6R2]+ can be successfully analysed by means of the ligand field theory for tetragonal fields. The ligands R (R = H2O, NH3, py, DMSO) are relatively labile and may be replaced by several ligands of varying donor strength. The spectra of trinuclear iron(III) acetates [Fe3O(CH3CO2)6R3]+ are poorly resolved but can be interpreted on the basis of a d5 configuration in octahedral fields. |
| Databáze: | Supplemental Index |
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