Carbonyl halides of the Group VI transition metals. XII. Isolation of halocarbonyls and halocarbonyl anions of molybdenum and tungsten.
| Autor: | Bowden, JA, Colton, R |
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| Zdroj: | Australian Journal of Chemistry; 1968, Vol. 21 Issue: 11 p2657-2661, 5p |
| Abstrakt: | Dibromotetracarbonylmolybdenum, Mo(CO)4Br2, and the dihalotetracarbonyltungsten compounds, W(CO)4X2 (where X = Cl, Br), have been isolated and characterized. These highly reactive compounds are all diamagnetic. The trihalotetracarbonyl anions [M(CO)4X3]- (M = Mo, W) have been isolated as their tetraethylammonium salts from the parent halocarbonyls. These yellow diamagnetic compounds are the first tetracarbonyl derivatives to be prepared from the parent halocarbonyls. |
| Databáze: | Supplemental Index |
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