Autor: |
Adams, RW, Barraclough, CG, Martin, RL, Winter, G |
Zdroj: |
Australian Journal of Chemistry; 1967, Vol. 20 Issue: 11 p2351-2356, 6p |
Abstrakt: |
Najor differences in magnetism are observed in the series CuXL where X = -OMe, Cl, Br, and L = -OMe, acac. Cu(OMe), exhibits linear antiferro- magnetism, CuCl(OMe) follows the Curie law with μeff 2.0 B.M., and CuBr(OMe) is only feebly paramagnetic. The magnetism of Cu(OMe) acac may be interpreted in terms of a singlet-triplet equilibrium with -J = 725 cm-1 (2.08 kcal mole-1). |
Databáze: |
Supplemental Index |
Externí odkaz: |
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