| Autor: |
Dwyer, FP, Goodwin, HA, Gyarfas, EC |
| Zdroj: |
Australian Journal of Chemistry; 1963, Vol. 16 Issue: 4 p544-548, 5p |
| Abstrakt: |
Bis(phenanthro1ine) and bis(bipyridine)ruthenium(~~) chelates have been prepared by the pyrolysis, at 300C, of phenanthrolinium tetrachlorophenanthrolineruthenate(III) and bipyridinium tetrachlorobipyridineruthenate(III). In the complexes [RuB2Cl2] the chelating base molecules are firmly bound but the chlorine atoms are replaceable by a variety of ligands such as water, pyridine, or acetylacetone. The complexes are spin-paired and show no tendency to disproportionation to the tris complexes, under normal experimental conditions. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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