Reactivity of a silanediyl towards nitriles — the role of azasilacyclopropenes as intermediates
| Autor: | Belzner, Johannes, Ihmels, Heiko, Noltemeyer, Matthias |
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| Zdroj: | Tetrahedron Letters; November 1995, Vol. 36 Issue: 45 p8187-8190, 4p |
| Abstrakt: | Cyclotrisilane 1a reacts with different nitriles to yield products 4–6. the formation of which is likely to proceed via initially generated azasilacylopropenes 3a–c. Disilane 6 represents the first example of a structurally characterized pentacoordinated silyl cyanide. |
| Databáze: | Supplemental Index |
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