Strategies for the Generation of Molecularly Imprinted Polymeric Nitroxide Catalysts

Autor: Anderson, C. D., Shea, K. J., Rychnovsky, S. D.
Zdroj: Organic Letters; October 2005, Vol. 7 Issue: 22 p4879-4882, 4p
Abstrakt: Two strategies for preparing catalytically active molecularly imprinted nitroxide-containing polymers are outlined. Both strategies rely upon the thermal rearrangement chemistry of tertiary amine N-oxides. To this end, several polymers were prepared and the polymeric nitroxides were revealed by oxidation with m-CPBA. All of the resulting polymeric catalysts proved to be competent mediators of the oxidation of alcohols.
Databáze: Supplemental Index