| Autor: |
Laus, G., Strasser, C. E., Holzer, M., Wurst, K., Purstinger, G., Ongania, K.-H., Rauch, M., Bonn, G., Schottenberger, H. |
| Zdroj: |
Organometallics; December 2005, Vol. 24 Issue: 25 p6085-6093, 9p |
| Abstrakt: |
The new heteronuclear ethene-bridged bimetallocene ferrocenylethenylcobaltocenium cation (fec-ene-coc+), as hexafluorophosphate and chloride, was prepared by Knoevenagel condensation of methylcobaltocenium PF6 and ferrocenecarbaldehyde. The chloride was obtained by anion exchange. X-ray crystal structure, cyclic voltammetry, and detailed solvatochromism data are reported and compared to those of related bimetallocenes, namely, the ethyne-bridged fec-yne-coc+, the directly linked fec-coc+, the new ethene-bridged ruc-ene-coc+, and the ethyne-bridged ruc-yne-coc+, as well as related termetallocenes. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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