New reaction pathway of dialkyl phosphorochloridites with salts of α-benzylideneaminocarboxylic acids. Direct synthesis of α-aminophosphonates from isostructural α-benzylideneaminocarboxylic acids

Autor: Bayandina, E., Davydova, E., Abaskalova, M., Musin, R., Al'fonsov, V.
Zdroj: Russian Chemical Bulletin; June 2005, Vol. 54 Issue: 6 p1492-1495, 4p
Abstrakt: The reaction of sodium N-benzylidenevalinate with dialkyl phosphorochloridites is accompanied by decarboxylation and yields diastereomeric N-(1-dialkoxyphosphoryl-2-methylpropyl)-N-(1-dialkoxyphosphorylbenzyl)amines.
Databáze: Supplemental Index