Synthesis and characterisation of ruthenium carbonyl fluorides
| Autor: | S. Coleman, Karl, H. Holloway, John, G. Hope, Eric |
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| Zdroj: | Journal of the Chemical Society, Dalton Transactions; January 1997, Vol. 1997 Issue: 10 p1713-1718, 6p |
| Abstrakt: | The oxidative fluorination of [Ru3(CO)12] with XeF2 in anhydrous HF afforded, in solution, cis-[RuF2(CO)4] as the major product with [RuF(CO)5]+, [Ru2F4(CO)7], [{RuF(CO)4}2(-F)]+, mer- and fac-[RuF3(CO)3]-, [{RuF2(CO)3}n] and [{RuF2(CO)3}(-F){Ru(CO)5 }]+ as minor products, all of which have been characterised by 13C, 19F and 13C-{19F} NMR spectroscopies. Removal of the HF solvent in vacuo yielded tetrameric [{RuF2(CO)3}4]. |
| Databáze: | Supplemental Index |
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