Autor: |
Avecilla, Fernando, Bastida, Rufina, de Blas, Andrés, E. Fenton, David, Macías, Alejandro, Rodríguez, Adolfo, Rodríguez-Blas, Teresa, García-Granda, Santiago, Corzo-Suárez, Raul |
Zdroj: |
Journal of the Chemical Society, Dalton Transactions; January 1997, Vol. 1997 Issue: 3 p409-414, 6p |
Abstrakt: |
Lanthanide(III) and yttrium(III) ions have been shown to behave as efficient metal templates in the synthesis of cryptates [M2L][NO3]6·xH2 O·ysolv (M = Y, La, Ce, Pr, Nd, Eu, Gd, Tb, Dy, Ho, Er, Tm or Yb) derived from the 2+3 condensation of tris(2-aminoethyl)amine with 2,6-diformyl-4-methylphenol. The complexes have been characterised by elemental analysis, molar conductivity, mass and IR spectroscopy and the yttrium complex was also characterised by NMR spectroscopy. The crystal structure of the dysprosium complex was determined. |
Databáze: |
Supplemental Index |
Externí odkaz: |
|