Transformation of diaminocarane on a triosmium cluster. Absolute configuration of a cluster with a bridging imidyl ligand
| Autor: | A. Maksakov, Vladimir, P. Kirin, Vladimir, V. Virovets, Aleksandr, A. Petukhov, Pavel, V. Tkachev, Alexey |
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| Zdroj: | Mendeleev Communications; November 25, 1999, Vol. 9 Issue: 6 p213-214, 2p |
| Abstrakt: | The C–H activation of an NMe2 group in diaminocarane coordinated to an Os3 cluster results in the formation of (R,S)-{Os3(CO)10(µ- H){µ,η2(N,C)- (4R,6R,8S,10S)-1,7,7,10-tetramethyl-1,3- diazatricyclo[3.5.0.0]dec-1-en-2-yl}} diastereomers. |
| Databáze: | Supplemental Index |
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