| Autor: |
Collison, David, David Garner, C., M. McGrath, Catherine, Frederick W. Mosselmans, J., Pidcock, Elna, D. Roper, Mark, G. Searle, Barry, M. W. Seddon, Jon, Sinn, Ekk, A. Young, Nigel |
| Zdroj: |
Journal of the Chemical Society, Dalton Transactions; December 21, 1998, Vol. 1998 Issue: 24 p4179-4186, 8p |
| Abstrakt: |
A detailed study of the soft X-ray photochemistry occurring in some nickel dithiocarbamate and xanthate complexes has shown that soft X-ray induced photoreduction of [NiIV(S2CNEt2)3][BF4] results in a NiII square-planar species and the rate is dependent on photon flux, photon energy and ligand set, but is essentially independent of temperature. Also, it has been demonstrated that [PPh4][NiII(S2COEt)3] is photoisomerised to a NiII square-planar species on exposure to soft X-rays. The implication for experiments on third generation synchrotron sources is discussed briefly. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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