| Autor: |
H. Doerrer, Linda, R. Galsworthy, Jane, L. H. Green, Malcolm, A. Leech, Michael, Müller, Matthias |
| Zdroj: |
Journal of the Chemical Society, Dalton Transactions; October 7, 1998, Vol. 1998 Issue: 19 p3191-3194, 4p |
| Abstrakt: |
The oxometal complexes [MoO2(η2-O-NR2)2], R 4;= 4;Et or CH2Ph, reacted with the strong Lewis acid B(C6F5)3 at their oxo functionality to give cis-[MoO{OB(C6F5)3}(η2-ONR2)2], (R 4;= 4;Et 1 or CH2Ph 2). Reaction of the peroxo complex [MoO(O2){η2-PhN(O)C(O)Ph}2] with the same Lewis acid led initially to the formation of [MoO(O2){B(C6F5)3}{η2-PhN(O)C(O)Ph}2] 3, which decomposes to form [MoO{OB(C6F5)3}{η2-PhN(O)C(O)Ph}2] 4. Compounds 1 and 4 have been characterised by X-ray crystallography. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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