Reactions of [M2(CO)10] (M 4;= 4;Mn or Re) with xenon bis[pentafluorooxo-tellurate(VI) and -selenate(VI)]

Autor: C. Crossman, Martin, G. Hope, Eric, J. Wootton, Lee
Zdroj: Journal of the Chemical Society, Dalton Transactions; June 7, 1998, Vol. 1998 Issue: 11 p1813-1818, 6p
Abstrakt: The oxidation of [M2(CO)10] (M 4;= 4;Mn or Re) with Xe(OEF5)2 (E 4;= 4;Se or Te) in dichloromethane at room temperature afforded [M(OEF5)(CO)5] (M 4;= 4;Mn or Re, E 4;= 4;Se or Te) which have been characterised by mass spectrometry, IR and NMR spectroscopies and extended X-ray absorption fine structure (EXAFS) spectroscopy
Databáze: Supplemental Index