| Autor: |
Geoffrey N. Cloke, F., R. Hanks, John, B. Hitchcock, Peter, F. Nixon, John |
| Zdroj: |
Chemical Communications; September 7, 1999, Vol. 1999 Issue: 17 p1731-1732, 2p |
| Abstrakt: |
The novel, fully structurally characterised, 14e-titanocene [Ti(η5-(P3C2But2)2] made by (i) cocondensation of titanium vapour with the phosphaalkyne ButCP (ii) reaction of ButCP with [Ti(η6-C6H5Me)2] at –78 °C or (iii) by heating TiCln with n(KP3C2But2) (n = 2, 3) in toluene at 110 °C, undergoes an unusual [2+2] cycloaddition reaction with ButCP to give [Ti(η5-P3C2But2)(η3-η2-P4C3But3)]. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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