Preparation and characterisation of a highly active bimetallic (Pd–Ru) nanoparticle heterogeneous catalyst†

Autor: Raja, Robert, Hermans, Sophie, S. Shephard, Douglas, F. G. Johnson, Brian, Raja, Robert, Sankar, Gopinathan, Bromley, Stefan, Meurig Thomas, John
Zdroj: Chemical Communications; August 21, 1999, Vol. 1999 Issue: 16 p1571-1572, 2p
Abstrakt: The mixed-metal carbonylate cluster [Pd6Ru6(CO)24]2– was used as a single-source precursor in the synthesis of a highly active hydrogenation catalyst (stoichiometry PdRu) which has been characterised by electron microscopy and X-ray absorption spectroscopy: PdRu readily hydrogenates alkenes and naphthalene (the latter predominantly to cis- decalin) under mild conditions
Databáze: Supplemental Index