Synthesis of an oxorhenium(V) corrolate from porphyrin with detrifluoromethylation and ring contraction
| Autor: | Kin Tse, Man, Zhang, Zeying, Shing Chan, Kin |
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| Zdroj: | Chemical Communications; June 7, 1998, Vol. 1998 Issue: 11 p1199-1200, 2p |
| Abstrakt: | Metallation of highly electron deficient 5,10,15,20-tetrakis(trifluoromethyl)porphyrin 1 with [Re2(CO)10] in refluxing PhCN resulted in a novel synthesis of oxorhenium(V) 5,10,15-tris(trifluoromethyl)corrolate 2 characterized by single crystal X-ray crystallography. |
| Databáze: | Supplemental Index |
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