The first sandwich silver cluster of a trinuclear cyclic gold(I) complex

Autor: Burini, Alfredo, Galassi, Rossana, R. Pietroni, Bianca, Burini, Alfredo, P. Fackler Jr., John, Galassi, Rossana, J. Staples, Richard
Zdroj: Chemical Communications; January 7, 1998, Vol. 1998 Issue: 1 p95-96, 2p
Abstrakt: A new type of metal sandwich structure [Ag{[Au(µ-N3,C2- bzim)]3}2]BF4·CH2Cl2 1, is formed by reacting the neutral, triangular cluster [Au(µ-N3,C2-bzim)]3 with Ag+; these units stack with two short intermolecular Au···Au distances of ca. 3.2 Å.
Databáze: Supplemental Index