Binding of bimetallic 1,10-phenanthroline ruthenium(II) complexes to DNA
| Autor: | M. O'Reilly, Fiona, M. Kelly, John |
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| Zdroj: | New Journal of Chemistry; April 3, 1998, Vol. 22 Issue: 3 p215-217, 3p |
| Abstrakt: | The binding of [(phen)2RuII(Mebipy)-(CH2)n-(bipyMe)RuII(phen)2]4+ (Mebipy=4-methyl-2,2′-bipyridyl-4′-, n=5 2a, 7 2b or 10 2c) to double-stranded DNA is found to be sensitive to the linker chain length n and to show a DNA-induced stacking interaction at high binding concentrations (e.g. [Nu]/[Ru]=1). |
| Databáze: | Supplemental Index |
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