| Abstrakt: |
Direct 1N‐amination of the triazole‐fused zinc phthalocyanine 2and oxidation of the formed amino derivative 3resulted in the generation of the very reactive intermediate, the dehydrometallophthalocyanine 4, which was not known previously. The latter was trapped in situ with different dienes, for example, furan, tetraphenylcyclopentadienone, and anthracene to form the corresponding Diels–Alder adducts. The products were characterized by 1H and 13C‐dept135 NMR, and UV/Vis spectroscopy, MALDI‐TOF mass spectrometry, and elemental analysis, which are fully in agreement with their structure. The developed synthetic procedure opens a simple and versatile pathway towards unsymmetrical peripheral modification of phthalocyanines, which is readily applicable to the micromol scale and is important for the design of new interesting Pc‐based systems. |
Plný text