| Autor: |
ColePresent address: School of Chemistry, Marcus L., Physics, Adelaide, The University of, Australia, South, 5, Davies, Aaron J., Jones, Cameron, Junk, Peter C. |
| Zdroj: |
New Journal of Chemistry; 2005, Vol. 29 Issue: 11 p1404-1408, 5p |
| Abstrakt: |
The lithium complexes LiNArCHNArpmdeta, where Ar 2,6-R2C6H3R Me 1, Et 2 and iPr 3 and pmdeta N,N,N′,N″,N″-pentamethyldiethylenetriamine, have been synthesised and their solid state structures determined by X-ray methods. Compounds 1–3comprise a Lipmdeta centre coordinated by a bulky formamidinate in either the E-synor E-antiisomeric form. The structures of compound 3and one unique molecular unit of compound 1E-antiisomer display coordination of the pendantamidinate imine, and can therefore be considered the first examples of η2:η1-CN,N′metal amidinate coordination. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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