Diferrocenyl(methylthio)cyclopropenylium Iodide in the Synthesis of2,3-Diferrocenyl-1-methylthio-1,3-dienes and -1,3,5-trienes

Autor:	Klimova Berestneva, Tatiana, Klimova, Elena I., Méndez Stivalet, José Manuel, Hernández-Ortega, Simón, Martínez García, Marcos
Zdroj:	European Journal of Organic Chemistry; October 2005, Vol. 2005 Issue: 20 p4406-4413, 8p
Abstrakt:	Diferrocenyl(methylthio)cyclopropenylium iodide reacts with organometallic compounds (methyllithium, benzyl- and ethylmagnesium chlorides, and allylmagnesium bromide) to yield 2,3-diferrocenyl-1-methylthio-1,3-dienes or -1,3,5-triene together with 3,3-dialkyl-1,2-diferrocenylcyclopropenes. We present data from X-ray diffraction analyses of (E)-2,3-diferrocenyl-1-methylthio- and (E,Z)-2,3-diferrocenyl-1-methylthio-4-phenyl-1,3-butadienes. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)
Databáze:	Supplemental Index
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