A Lutetium Cyclopentadienyl-Phosphazene Constrained Geometry Complex (CGC): First Isolobal Analogues of Group 4 Cyclopentadienyl-Silylamido CGC SystemsPart 3 in the series “Organophosphorus(V) Ligands for Coordination and Organometallic Chemistry”; for Part 2 see: K. A. Rufanov, B. Ziemer, M. Meisel, Dalton Trans. 2004, 3808–3809.Dedicated to Prof. Dr. Herbert Schumann on the occasion of his 70th birthday

Autor: Rufanov, Konstantin A., Petrov, Alex R., Kotov, Vasili V., Laquai, Frédéric, Sundermeyer, Jörg
Zdroj: European Journal of Inorganic Chemistry; October 2005, Vol. 2005 Issue: 19 p3805-3807, 3p
Abstrakt: C5Me4HPMe2 reacts with 1-adamantyl azide to form the firstexample of a new family of cyclopentadienylideneaminophosphorane ligands (1). Metallation of 1 with Lu(CH2SiMe3)3(THF)2 leads to the first cyclopentadienyl-phosphazene CGC 2, isolobal to known group 4 cyclopentadienyl-silylamido CGC systems. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)
Databáze: Supplemental Index
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