Autor: |
Campbell, K., Ooms, K. J., Wasylishen, R. E., Tykwinski, R. R. |
Zdroj: |
Organic Letters; August 2005, Vol. 7 Issue: 16 p3397-3400, 4p |
Abstrakt: |
Hyperpolarized 129Xe NMR spectroscopy is used to establish the solid-state porosity of shape-persistent macrocycles with either an organic or metal−organic framework. These studies show that even upon removal of cocrystallized solvent molecules, the macrocycles maintain a porous or channeled structure. The technique can provide valuable information about systems for which X-ray crystallographic analysis is not feasible. |
Databáze: |
Supplemental Index |
Externí odkaz: |
|