Asymmetric Transfer Hydrogenation in Water with a Supported Noyori−Ikariya Catalyst

Autor: Li, X., Wu, X., Chen, W., Hancock, F. E., King, F., Xiao, J.
Zdroj: Organic Letters; September 2004, Vol. 6 Issue: 19 p3321-3324, 4p
Abstrakt: The poly(ethylene glycol)-supported ruthenium precatalyst shown above is highly effective for asymmetric transfer hydrogenation of unfunctionalized aromatic ketones by HCOONa in neat water, affording fast rates, good to excellent enantioselectivities, and outstanding reusability.
Databáze: Supplemental Index