| Autor: |
Slootweg, J. C., Zeist, W.-J. van, Kanter, F. J. J. de, Schakel, M., Ehlers, A. W., Lutz, M., Spek, A. L., Lammertsma, K. |
| Zdroj: |
Organometallics; October 2005, Vol. 24 Issue: 21 p5172-5175, 4p |
| Abstrakt: |
A phosphaspiropentene is the plausible kinetic product from the addition of dichlorocarbene to a phosphatriafulvene, which rearranges to a novel P-substituted triafulvene. The calculated barrier of 18.6 kcal mol-1 for this process is consistent with the temperature of −40 °C at which this reaction proceeds. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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