Autor: |
G. Back, Thomas, Minksztym, Kazimierz |
Zdroj: |
Chemical Communications; September 21, 1997, Vol. 1997 Issue: 18 p1759-1760, 2p |
Abstrakt: |
The free-radical addition of phenyl trichloromethyl selenide to alkenes affords 2-phenylseleno-1-trichloromethylalkanes, which can be converted into α,β-unsaturated carboxylic acids or amides by base-promoted dehydrochlorination, followed by [2,3]sigmatropic rearrangement of the corresponding selenoxides in the presence of water or diethylamine, respectively. |
Databáze: |
Supplemental Index |
Externí odkaz: |
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