| Autor: |
K. Whittlesey, Michael, N. Perutz, Robin, Greener, Bryan, H. Moore, Madeleine |
| Zdroj: |
Chemical Communications; January 21, 1997, Vol. 1997 Issue: 2 p187-188, 2p |
| Abstrakt: |
The bifluoride complex, trans-[Ru(dmpe)2(H)(HF2)] (dmpe = Me2PCH2CH2PMe2), is generated by reaction of cis-[Ru(dmpe)2H2] either with fluoroarenes (C6F6, C6F5H and others) or by reaction with Et3N·3HF; its solid-state structure, established crystallographically, reveals a Ru(η1-FHF) moiety with a long Ru–F bond and an F···F distance close to that in bifluoride salts, while the presence of the same complex in solution is shown by low-temperature NMR spectra. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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