| Autor: |
P. Hsung, Richard, F. Quinn, John, A. Weisenberg, Brian, D. Wulff, William, P. A. Yap, Glenn, L. Rheingold, Arnold |
| Zdroj: |
Chemical Communications; March 21, 1997, Vol. 1997 Issue: 6 p615-616, 2p |
| Abstrakt: |
The cyclohexadienone annulation of a β,β-disubstituted vinyl chromium carbene complex and a chiral prop-2-ynylic ether results in high 1,4-asymmetric induction at the newly formed quaternary carbon; the stereochemical information from the prop-2-ynylic ether is initially transfered to the chromium coordination sphere and then to the quaternary carbon of the cyclohexa-2,4-dienone. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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