| Autor: |
Bartik, Kristin, Luhmer, Michel, Heyes, Stephen J., Ottinger, Robert, Reisse, Jacques |
| Zdroj: |
Journal of Magnetic Resonance - Series B; November 1995, Vol. 109 Issue: 2 p164-168, 5p |
| Abstrakt: |
129Xe NMR has been used to investigate intermolecular interactions between xenon and α-cyclodextrin in H2O and in DMSO. Nuclear Overhauser enhancement effects confirmed the formation of a xenon–cyclodextrin complex. Chemical shifts were measured in solutions containing different concentrations of α-cyclodextrin and in solutions containing linear oligosaccharides. The experimental data are interpreted on the basis of a three-site model for xenon. The binding characteristics of the xenon–cyclodextrin system, including the129Xe NMR chemical shift in the cavity and the equilibrium constants, were determined and are discussed. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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