| Autor: |
Wijdeven, M. A., Botman, P. N. M., Wijtmans, R., Schoemaker, H. E., Rutjes, F. P. J. T., Blaauw, R. H. |
| Zdroj: |
Organic Letters; September 2005, Vol. 7 Issue: 18 p4005-4007, 3p |
| Abstrakt: |
The stereoselective total synthesis of the novel quinolizidine alkaloid (+)-epiquinamide is presented, starting from the amino acid l-allysine ethylene acetal. Key steps in the synthesis involved a highly diastereoselective N-acyliminium ion allylation and a ring-closing metathesis reaction to provide the bicyclic skeleton. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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