Topochemical solid-state reactions and problems of selective synthesis of fullerene derivatives

Autor: Borshchevskii, A. Ya., Sidorov, L. N., Chilingarov, N. S., Aleshina, V. E.
Zdroj: Russian Chemical Bulletin; January 2005, Vol. 54 Issue: 1 p31-50, 20p
Abstrakt: Abstract The characteristic features of polyaddition of small functional groups to fullerenes are considered. The review summarizes the results of experimental and theoretical studies of topochemical solid-state fluorination of fullerene C60 with inorganic variable-valence transition metal fluorides and elemental fluorine in chemically active matrices. The thermodynamic and kinetic aspects of the reactions and the factors responsible for selectivity are considered.
Databáze: Supplemental Index