Autor: |
Borshchevskii, A. Ya., Sidorov, L. N., Chilingarov, N. S., Aleshina, V. E. |
Zdroj: |
Russian Chemical Bulletin; January 2005, Vol. 54 Issue: 1 p31-50, 20p |
Abstrakt: |
Abstract The characteristic features of polyaddition of small functional groups to fullerenes are considered. The review summarizes the results of experimental and theoretical studies of topochemical solid-state fluorination of fullerene C60 with inorganic variable-valence transition metal fluorides and elemental fluorine in chemically active matrices. The thermodynamic and kinetic aspects of the reactions and the factors responsible for selectivity are considered. |
Databáze: |
Supplemental Index |
Externí odkaz: |
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