| Autor: |
Li, Xiaoyan, Sun, Hongjian, Klein, Hans‐Friedrich, Flörke, Ulrich |
| Zdroj: |
Zeitschrift für anorganische und allgemeine Chemie; August 2005, Vol. 631 Issue: 10 p1929-1931, 3p |
| Abstrakt: |
The mer‐octahedral complexes(2‐carbonyl)(4‐Me)(6‐tBu)phenolato[C,O]hydridotris(trimethylphosphine)cobalt(III) (1) or ‐(1‐carbonyl)(2‐oxo)(1,2‐diphenylethene)[C,O]hydridotris(trimethylphosphine)cobalt(III) (2) via formal insertion of propynoic acid ethyl ester into Co‐H functions afford pentacoordinate vinylcobalt(III) 3and 4, respectively, that are diamagnetic and attain a square pyramidal structure as exemplified by an X‐ray diffraction analysis of 3. |
| Databáze: |
Supplemental Index |
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