Dynamic combinatorial olefin metathesis: templated synthesis of porphyrin boxesElectronic supplementary information (ESI) available: detailed synthetic procedure and characterization of Zn4.TPyPby means of NMR and UV-VIS spectroscopy, MALDI-TOF MS and GPC. See http://www.rsc.org/suppdata/cc/b5/b503619d/This article is dedicated to the late Professor Ian Rothwell, Associate Editor Inorganic Chemistry, ChemComm.

Autor: van Gerven, Paul C. M., Elemans, Johannes A. A. W., Gerritsen, Jan W., Speller, Sylvia, Nolte, Roeland J. M., Rowan, Alan E.
Zdroj: Chemical Communications; 2005, Vol. 2005 Issue: 28 p3535-3537, 3p
Abstrakt: A porphyrin macrocyclic square is efficiently prepared by a dynamic combinatorial approach to olefin metathesis and shown by scanning tunneling microscopy STM to self-assemble into highly ordered arrays on a graphite surface.
Databáze: Supplemental Index