| Autor: |
Yonker, C. R., Wallen, S. L. |
| Zdroj: |
Applied Spectroscopy; June 1996, Vol. 50 Issue: 6 p781-784, 4p |
| Abstrakt: |
The investigation of the photoreversible fulgide Aberchrome-540 as a function of pressure and temperature with the use of nuclear magnetic resonance (NMR) detection is described. This technique demonstrates the novel combination of high-pressure NMR and laser photolysis with the use of fiber optics for the conversion of the fulgide on-line in the instrument. Investigation of the photolysis of Aberchrome-540 to 2.0 kbar and 120 °C is reported. Extension of this technique should allow the investigation of photoinitiated reaction kinetics and equilibria as a function of pressure and temperature with simultaneous structure characterization by NMR. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
|
