Synthesis of an Analogue of the Marine Polypropionate Tridachiahydropyrone

Autor: Jeffery, D. W., Perkins, M. V., White, J. M.
Zdroj: Organic Letters; February 2005, Vol. 7 Issue: 3 p407-409, 3p
Abstrakt: A novel approach to the formation of the unusual pyrone-containing ring systems as found in polypropionate metabolites from the Tridachia family of marine molluscs has been developed. This approach includes an intramolecular cyclization of a β-keto acid onto a cyclohexenone ring to afford a fused, bicyclic pyrone.
Databáze: Supplemental Index