Preparation and Properties of RMg(macrocycle)⁺ Cations with Accompanying Anions Derived from Acidic Hydrocarbons or a Hindered Phenol

Autor:	Pajerski, A. D., Squiller, E. P., Parvez, M., Whittle, R. R., Richey, H. G., Jr.
Zdroj:	Organometallics; February 2005, Vol. 24 Issue: 5 p809-814, 6p
Abstrakt:	Reactions of an R2Mg compound, a macrocycle, and fluorene (FlH) or indene (InH) can form RMg(macrocycle)+ and Fl- or In-. Some reactions of RMgOAr (Ar = 2,6-di-tert-butylphenyl) and macrocycles form RMg(macrocycle)+RMg(OAr)2-. Crystal structures of MeMg(1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane)+Cp-, i-BuMgOAr(18-crown-6), and EtMgOAr(tetramethylethylenediamine) are reported.
Databáze:	Supplemental Index
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