Highly enantioselective dynamic kinetic resolution and desymmetrization processes by cyclocondensation of chiral aminoalcohols with racemic or prochiral δ-oxoacid derivativesElectronic supplementary information (ESI) available: Typical experimental procedure and 1H and 13C NMR spectra for all new compounds. See http://www.rsc.org/suppdata/cc/b4/b413937b/
| Autor: | Amat, Mercedes, Bassas, Oriol, Pericàs, Miquel A., Pastó, Mireia, Bosch, Joan |
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| Zdroj: | Chemical Communications; 2005, Vol. 2005 Issue: 10 p1327-1329, 3p |
| Abstrakt: | Cyclocondensation reactions of aminoalcohols 7and 8with racemic or prochiral δ-oxoacid derivatives provide polysubstituted lactams with high enantioselectivity in a process that involves dynamic kinetic resolution andor desymmetrization of enantiotopic or diastereotopic ester groups. |
| Databáze: | Supplemental Index |
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