| Abstrakt: |
A new complex, hexadimethylsulfoxidenickel(II) tetraisothiocyanatozincate [Ni(DMSO) 6][Zn(NCS)4](I), is synthesized. Its crystal structure is determined by X-ray diffraction analysis. Compound I forms light green, monoclinic crystals shaped like plates: a = 8.4358(8) Å , b = 21.655(2) Å, c = 10.8351(8) Å β = 105.162(7)°, V = 1910.4(3) Å3, space group P21/m, Z = 2, ρ(calcd) = 1.434 g/cm 3, µ= 1.699mm −1. The Zn atom has a tetrahedral environment, while the Ni atom has an octahedral environment. |
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