Reaction of 2-acetyl-5-methyl-2H-1,2,3-diazaphosphole with butane-2,3-diol

Autor: Khusainova, Narkis G., Mostovaya, Olga A., Azancheev, Nail M., Litvinov, Igor A., Krivolapov, Dmitry B., Cherkasov, Rafael A.
Zdroj: Mendeleev Communications; September 2004, Vol. 014 Issue: 5 p212-214, 3p
Abstrakt: The reaction of 2-acetyl-5-methyl-2H-1,2,3-diazaphosphole with (rac)-butane-2,3-diol at temperatures below 0 C leads to the formation of a hydrospirophosphorane containing both a diazaphospholene and a dioxaphospholane ring system and a β-hydroxyalkoxy-1,2,3-diazaphospholene. On heating, these products form a hydrospirotetraoxaphosphorane, its tautomeric monocyclic β-hydroxyalkylphosphite and N-acetyl-N'-isopropylidene-hydrazine.
Databáze: Supplemental Index