| Abstrakt: |
Photocatalytic reactions are widely investigated as a green chemistry approach towards organic molecule synthesis. Herein, we fabricated (MWCNT/TiO2) composite materials which are beneficial in the photocatalytic synthesis of benzopinacol on irradiation with UV–visible light. The precursor-layer-coating (PLC) method was successfully employed to produce a series of composite materials, X%-MWCNT/TiO2, where (X = 2, 4, 6, and 8 % w/w). The XRD confirmed major-anatase and minor-brookite TiO2along with MWCNT in the composite. FE-SEM, HR-TEM, and EDAX revealed the expected composite microstructure, morphology, and compositional details. The nanosized (10 ̶30 nm), spherically shaped TiO2particles were seen integrated to the MWCNT surface. The BET-surface area of the mesoporous composites enhanced from 83.77 to 114.39 m2/g as the MWCNT loading increased from 2 % to 8 %. The optical studies indicated a marginal shift in absorption edge towards longer wavelength with % MWCNT loadings. The band gap (Eg) was reduced and the charge pair recombination rate retarded. The PL, Raman and XPS studies supported the heterojunction formation at the interface. The photocatalytic activity was evaluated based on the % conversion efficiency of benzophenone to benzopinacol in the presence of light and composite as a photocatalyst. The 6 %-MWCNT/TiO2demonstrated the highest photoactivity with an additional 34 % and 25 % yield in UV and sunlight respectively compared to bare TiO2. The effective light absorption, electronic excitation, charge pair separation and transfer mechanism at the MWCNT/TiO2interface were responsible for enhanced photoactivity. The current investigation provided a promising strategy to produce hybrid photocatalytic material for organic molecule synthesis. |
Full Text from ScienceDirect